Reaction of Sodium Azide with 1,1'–Dicyclohexenyl–Diepoxides
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زبان مدرک
Englishچکیده
Nucleophilic ring opening of dl and meso 1,1¢- dicyclohexenyl diepoxides by sodium azide in dioxane and aqueous alcoholic medium give the corresponding azidoalcohols. The obtention of departure diepoxides from diazidoalcohols by the reaction with sodium hydride shows the anti position of OH and N3 groups.
کلید واژگان
Sodium azide1,1' – Dicyclohexenyl – diepoxides
Nucleophilic opening
Azido-alcohols
Trans diaxial
Organic Chemistry
شماره نشریه
2تاریخ نشر
2003-12-011382-09-10
ناشر
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRسازمان پدید آورنده
Department of Chemistry, Faculty of Science, University of Tehran, Tehran, I.R. IRANDepartment of Chemistry, Faculty of Science, University of Tehran, Tehran, I.R. IRAN
Department of Chemistry, Faculty of Science, University of Tehran, Tehran, I.R. IRAN
Research Institute of Petroleum Industry, National Iranian Oil Company, Tehran, I.R. IRAN
