conformational properties and the anomeric effect study of phosphinanes
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زبان مدرک
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Ab initio HF/6-31G* Methode was employed to calculate the bond length in 2- phosphinanes when electronegative groups was at C-2 tend axial and equatorial positions. The magnitude of the anomeric effect depends on the nature of the substituent, the effect of the substituent can be seen by comparing the bond length in 2-chloro and 2- boromo substituented phosphinanes. The effect of anomeric effect have been effected on the bond length in 2-phosphinanes.
کلید واژگان
anomeric effect2- phosphinane
bond length
axial and equatorial position
Ab initio calculations
شماره نشریه
2تاریخ نشر
2014-09-011393-06-10
ناشر
Islamic Azad University Ahvaz Branchسازمان پدید آورنده
Department of chemistry, Science and Reaserch branch, Islamic azad university, Tehran, IranDepartment of chemist r,y Mahshahr branch, Islamic azad university, Mahshahr, Iran
Department of chemist r,y Mahshahr branch, Islamic azad university, Mahshahr, Iran
Department of chemist r,y Mahshahr branch, Islamic azad university, Mahshahr, Iran
