Consideration of C-H…O interaction in the heterocyclic organic-inorganic hybrid material: tri-prolinium12- phosphomolibdate heteropolyoxometalate
چکیده
Crystallographic data analyses indicate that three types of prolinium cations, along with two types of hydrogen bonding, produce and stabilize the helical structure of triprolinium 12-phosphomolybdate. There are similarities between this organic-inorganic compound and peptides/proteins. The stronger “conventional" hydrogen bonds and the less common C-H…O attractions play critical roles in generating and stabilizing the DNA-like network.
کلید واژگان
ProlineHydrogen bonding
Polyoxometallates
Molybdenum
Hybrid
Keggin
Protein
Peptide
شماره نشریه
1تاریخ نشر
2011-05-011390-02-11
ناشر
Islamic Azad University Ahvaz Branchسازمان پدید آورنده
aDepartment of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436, IranaDepartment of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436, Iran
aDepartment of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436, Iran
aDepartment of Chemistry, Ferdowsi University of Mashhad, Mashhad P.O. Box 917791436, Iran
bDepartment of Chemistry, Georgetown University, Washington, DC 20057, USA
