Efficient oxidation of sulfides using a molybdenum(VI)–dioxo complex containing an benzimidazole ligand

Abstract

For the first time, dioxomolybdenum(VI) complex with the general formula [MoO₂L₂] containing a N-O bidentate ligands (HL=2-(o-aminophenyl)- benzimidazole) has been used for the oxidation of sulfides. Elemental analyses (carbon, hydrogen, nitrogen), FT-IR and Uv-Visble spectra and ¹HNMR analysis agree well with the proposed stoicheiometry of the complex [MoO₂L₂]. A variety of sulfides were smoothly converted into the corresponding sulfoxide catalyzed by this molybdenum complex. The effect of the reaction conditions on the oxidation was studied by varying the amount of the catalyst, the amount of oxidant (UHP) and solvent type. Good yields with excellent selectivities were obtained in most cases.