Chemical Modification of Lignite and Investigation of its Properties in Controlling Fluid Loss of Oil Well Cement Slurries

Abstract

The aim of this research was to produce a convenient additive for enhancing the properties, especially the fluid loss, of oil well cement slurries. In this regard, a variety of drilling/cementing chemical additives known as fluid loss controllers were prepared through derivatization and chemical modification of lignite. Lignite-based graft copolymers were synthesized using different groups of acrylic monomers via aqueous the free radical polymerization method. Then, it was allowed to react with sulfomethylating agents to enhance its water solubility. Subsequently, a comparative sulfomethylated lignite was prepared and employed as the backbone in the free radical polymerization. ATR-FTIR and elemental analyses were performed to demonstrate the structures of the fluid loss controller and incorporated elements. The performance of these additives in improving the properties of oil well cement slurries was investigated through analyzing the quality of fluid loss controller in saline saturated slurries. Under similar desired well conditions, i.e. a compressive strength of 800-1100 psi, a thickening time of 400 minutes, and a viscosity of 25 cP, a fluid loss below 130 ml API was obtained. The best standard performance was assigned to the cement slurry which employed sulfomethylated lignite graft copolymer.