Estimation of the Diffusion Coefficient and Hydrodynamic Radius (Stokes Radius) for Inorganic Ions in Solution Depending on Molar Conductivity as Electro-Analytical Technique-A Review

Abstract

Diffusion coefficient (D) and radiuses of inorganic charge ions (R) in different environments is of importance in scientific fields, explaining certain features of ions. D values were obtained using the Einstein-Smoluchowski equation depending on limiting molar conductivity (λ^o) of inorganic charge ions. Inorganic ions have D values at the range of 1−3×10⁻⁹m².s^-1,except hydroxyl and hydrogen ion (5.2×10⁻⁹ and 9.1×10⁻⁹ m².s^-1, respectively). The hydrodynamic radius R for diffusing ions was calculated using the Stokes–Einstein equation based on D values. Inorganic ionshaveR, values at the range of 1−3×10⁻¹⁰m, except hydroxyl and hydrogen ion (R=0.47×10⁻¹⁰and 0.27×10⁻¹⁰m, respectively).