ELECTROCHEMICAL BEHAVIOR OF 1 - HYDROXYPYRIDINE 2-THIONE AND ITS VANADIUM COMPLEX

Abstract

Electrochemical behavior of I-hydroxypyridine-2-thione and its vanadium complex is studied using polarographic techniques. Polarograms of ligand and that of the complex is shown with diffusion characteristics of the waves. Cyclic voltagram of thione is investigated which shows that a reversible oxidation reduction of one electron process is taking place. PKa of the thione is found to be in close agreement with the previous findings