نمایش مختصر رکورد

dc.contributor.authorPakiari, Alien_US
dc.contributor.authorDehghanpisheh, Elhamen_US
dc.contributor.authorHaghighi, Behzaden_US
dc.date.accessioned1399-07-08T19:04:19Zfa_IR
dc.date.accessioned2020-09-29T19:04:19Z
dc.date.available1399-07-08T19:04:19Zfa_IR
dc.date.available2020-09-29T19:04:19Z
dc.date.issued2015-12-01en_US
dc.date.issued1394-09-10fa_IR
dc.date.submitted2015-07-12en_US
dc.date.submitted1394-04-21fa_IR
dc.identifier.citationPakiari, Ali, Dehghanpisheh, Elham, Haghighi, Behzad. (2015). How to Change the Redox Potential of Guanine?. Physical Chemistry Research, 3(4), 341-346. doi: 10.22036/pcr.2015.11247en_US
dc.identifier.issn2322-5521
dc.identifier.issn2345-2625
dc.identifier.urihttps://dx.doi.org/10.22036/pcr.2015.11247
dc.identifier.urihttp://www.physchemres.org/article_11247.html
dc.identifier.urihttps://iranjournals.nlai.ir/handle/123456789/58433
dc.description.abstractDue to some important applications of guanine electrode in scientific and technology research such as electro-chemical DNA based biosensors, and a problem of high redox potential of guanine (0.81 V), our research study concentrates on reducing guanine redox potential by substituting Cu, Ag, Au, CH<sub>3</sub>, C<sub>2</sub>H<sub>5</sub> and Cl on sites of 1, 2 and 9 of guanine. A 5.0% reduction of redox potential for 9-Ag-guanine was the sign of favorable result. In order to have further lower potential, sliver clusters (Ag<sub>2 </sub>andAg<sub>3</sub>) were used. The obtained percentages of reduction of potentials were 53.6% and 36.8% for 9-Ag<sub>2 </sub>and 9-Ag<sub>3</sub>-guanine, respectively. In this research, Gaussian 09 was used and DFT was applied with long-range corrected xc-functional (LC-BLYP).en_US
dc.format.extent186
dc.format.mimetypeapplication/pdf
dc.languageEnglish
dc.language.isoen_US
dc.publisherIranian Chemical Societyen_US
dc.relation.ispartofPhysical Chemistry Researchen_US
dc.relation.isversionofhttps://dx.doi.org/10.22036/pcr.2015.11247
dc.subjectRedox Potentialsen_US
dc.subjectGuanineen_US
dc.subjectSubstitutionsen_US
dc.subjectBiosensoren_US
dc.subjectElectrochemistryen_US
dc.titleHow to Change the Redox Potential of Guanine?en_US
dc.typeTexten_US
dc.typeRegular Articleen_US
dc.contributor.departmentShiraz Universityen_US
dc.contributor.departmentShiraz University, Chemistry Department.en_US
dc.contributor.departmentChemistry Dept. Shiraz Universityen_US
dc.citation.volume3
dc.citation.issue4
dc.citation.spage341
dc.citation.epage346


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