Polysulfone Ultrafiltration Membranes Modified with Carbon-Coated Alumina Supported NiTiO2 Nanoparticles for Water Treatment: Synthesis, Characterization and Application

Abstract

<span class="fontstyle0">This paper reports on the synthesis and characterisation of polysulfone (PSf) ultrafltration (UF) membranes modifed with carbon coated alumina Ni-doped titanium dioxide (CCA/Ni-TiO</span><span class="fontstyle0" style="font-size: 4pt;">2</span><span class="fontstyle0">) nanoparticles. The syntheses of the membranes was carried out using the phase inversion process. The permeate flux of the membrane modifed with 0.25% CCA/Ni-TiO</span><span class="fontstyle0" style="font-size: 4pt;">2 </span><span class="fontstyle0">nanoparticles (213.5±6.40 L.m</span><span class="fontstyle0" style="font-size: 4pt;">-2</span><span class="fontstyle0">.h</span><span class="fontstyle0" style="font-size: 4pt;">-1</span><span class="fontstyle0">) was found to be higher than that of the unmodifed membrane (130.95±4.50 L.m</span><span class="fontstyle0" style="font-size: 4pt;">-2</span><span class="fontstyle0">.h</span><span class="fontstyle0" style="font-size: 4pt;">-1</span><span class="fontstyle0">) at 13.8 bar. The membrane modifed with 0.50% CCA/NiTiO</span><span class="fontstyle0" style="font-size: 4pt;">2 </span><span class="fontstyle0">nanoparticles had the lowest permeate flux at 105.18±4.52 L.m</span><span class="fontstyle0" style="font-size: 4pt;">-2</span><span class="fontstyle0">.h</span><span class="fontstyle0" style="font-size: 4pt;">-1</span><span class="fontstyle0">. The improved water permeability was brought about by the hydrophilicity resulting from introduction of the hydroxyl groups of the nanoparticles. At 13.8 bar, the NaCl salt rejection properties of the mixed matrix membranes were relatively higher (31.38±1.23%) for the 0.25% PSf/CCA/Ni-TiO</span><span class="fontstyle0" style="font-size: 4pt;">2 </span><span class="fontstyle0">membranes compared to that of the unmodifed PSf membrane (12.76±1.10%). Similar observations were made for the Cr</span><span class="fontstyle0" style="font-size: 4pt;">3+ </span><span class="fontstyle0">heavy metal rejection, which ranged between 56.27±2.54% and 60.48±2.52% for the modifed membranes. These results have demonstrated the role the electrostatic effects of the nanoparticles play in the rejection mechanism of the modifed membranes when compared to the unmodifed membranes. Unmodifed membranes were found to reject 28.32±1.65% of Cr</span><span class="fontstyle0" style="font-size: 4pt;">3+ </span><span class="fontstyle0">heavy metals at the same pressure. Over a period of 180 minutes, the membranes were found to be more photocatalytically active towards bromophenol blue, and a maximum photodegradation efciency of 81% was achieved compared to only 50.5% for methyl orange. The photo-degradation process for both dyes followed a pseudo-frst-order reaction rate. </span>