Volume 2, Issue 1
مرور بر اساس
ارسال های اخیر
-
The Flight of the Monarch: [Cu(L)(CH3CN)(PPh3)]ClO4 (L = 2,5-Diphenyl-3,4-bis(2-pyridyl) Cyclopenta-2,4-dien-1-one)
(Iranian Chemical Society, 2018-12-01)The mononuclear complex [Cu(L)(CH3CN)(PPh3)]ClO4, (1), (L= 2,5-diphenyl-3,4-bis(2-pyridyl)cyclopenta-2,4-dien-1-one), has been synthesized and investigated by elemental analysis, IR, 1H NMR, UV-Vis spectroscopic methods ...
-
The Kinetic and Thermal Degradation Studies of N-(4-Acetyl-phenyl)-acetimidic Acid Pyridine-3-yl ester Metal(II) Complexes
(Iranian Chemical Society, 2018-12-01)Schiff base complexes of transition metals are of particular interest to inorganic chemists because of their structural, spectral and chemical properties, which are often strongly dependant on the nature of the ligand ...
-
Solvatochromic Properties of Heteroleptic Copper(II) Complexes Containing N,N,N',N'-Tetramethylethylenediamine and 2-Aacetylcyclopentanone Ligands
(Iranian Chemical Society, 2018-12-01)Three new heteroleptic copper(II) complexes, [(tmen)Cu(dike)H2O]X where tmen = N,N,N',N'-tetramethylethylenediamine, dike = 2-acetylcyclopentanone anion and X= ClO4- (1), Cl- (2) and Br- (3) are prepared and characterized ...
-
Mild and Efficient Oxidation of Alcohols with NaIO4 Catalyzed by a Manganese Porphyrin-polyoxometalate Hybrid Material
(Iranian Chemical Society, 2018-12-01)Efficient and selective oxidation of alcohols with NaIO4 catalyzed by an organic-inorganic hybrid material in which manganese(III)5,10,15,20-tetrakis(4-aminophenyl)porphyrin chloride, MnIII(TAPP)Cl, is covalently linked ...
-
On the Polymorphism of 12-Tungstoborate Heteropolyanion: Structure Determination and Its Functionalization with L-proline
(Iranian Chemical Society, 2018-12-01)A new structure related to previously reported structure of 12-tungstoborate Keggin-type polyoxometalate, K5[BW12O40], was synthesized and its characterization by single crystal X-ray diffraction shows the polymorph ...
-
Synthesis and Crystal Structure of Cobalt(III) Complexes of Salen Type Schiff Bases and Tertiary Phosphanes as Ligands
(Iranian Chemical Society, 2018-12-01)The new [Co(Salen)(PBu3)2]ClO4, [Co(Salen)(PBu3)2]BF4, [Co(Salpn)(PBu3)2]ClO4 and [Co(Salen)(PMe2Ph)2]ClO4 ( where salen = bis(salisylaldehyde)ethylenediimine)) complexes were synthesiszed and chracterized by IR, UV-Vis, ...
-
Plumbum(II) and Zinc(II) Complexes with 5-Chlorosalicylic Acid: Structure and Propertie
(Iranian Chemical Society, 2018-12-01)Abstract: Two new transition metal complexes, containing the acidic ligand 5-chlorosalicylic acid (H2L5), and 1,10-phenanthroline（phen） and 1,3-Di(4-pyridyl)propane (bpp) as secondary ligands are reported. They are formulated ...
-
Natural Bond Orbital (NBO) Study of (5H-tetrazol-1-yl)(triphenylphosphine)gold [Au(tetz)(PPh3)]
(Iranian Chemical Society, 2018-12-01)In this research work, we studied theoretically the structural properties of (5H-tetrazol-1-yl)(triphenylphosphine)gold or [Au(tetz)(PPh3)] by density functional theory (DFT) method at LANL2DZ level. All calculations were ...
-
Synthesis and Characterization of Binuclear Zn(II) Complex of N2O2S Symmetrical Potentially Pentadentate Schiff Base Ligand
(Iranian Chemical Society, 2018-12-01)The reactions of 1 - chloro - 2 - nitro benzene with 2 - Amino thio phenol yield the 2 - ( ( nitro phenyl ) thio ) aniline and then 2 , 2' - thio dianiline of this compound was prepared . Also the symmetrical potentially ...
-
Synthesis, Characterization and Theoretical Studies of a New Macroacyclic Schiff-Base Ligand Containing Piperazine Moiety and Related Mn(II), Cu(II), Ni(II) and Cd(II) Complexes
(Iranian Chemical Society, 2018-12-01)Four new [NiH2L](ClO4)2 (1), [CuH2L](ClO4)2 (2), [MnH2L](ClO4)2 (3) and [CdH2L](ClO4)2 (4), complexes were prepared by the reaction of a new Schiff base ligand and Cu(II), Ni(II), Mn (II) and Zn (II) metal ions in equemolar ...
