An investigation on the adsorption behavior of Sb (III) on a cationic ion exchange resin in Fixed-bed column: experimental design and breakthrough curves modeling

Abstract

The purpose of this study is to investigate and optimize parameters effective on continuous adsorption and elution and study of the corresponding breakthrough curve models for the removal of one of the main pollutants found when copper is extracted and refined. Mining has a long history of producing toxic waste so there is a heightened sense of urgency for finding ways to protect the environment especially during the initial production stages. The contaminants in water and mine wastewater are key issues in the reuse of water resources. In this study, adsorption by fixed-bed column which is usually applied for removing organic contaminants from the aqueous phase is investigated for adsorption of the antimony on a commercially available cationic resin Purolite S957 and the kinetics of adsorption is explored by establishing breakthrough and resin saturation times. Concentration and feed flow rate affect the kinetics of adsorption on a fixed-bed resin and were determined both experimentally as well as through optimization by a two-level factorial experimental design using Central Composite Design (CCD). Experiments were carried out at constant temperature and pH of 55 ℃ and 8 respectively that were determined based on optimal conditions for fixed resin content of 25 g. The breakthrough test results suggest Bohart-Adams model better fitted the experimental data compared to Thomas and Yan models with R² of 0.964. Moreover, elution of pure antimony occurred at 15 BV of elution solution and maximum concentration of antimony was achieved at about 300 mg.L- 1