| dc.contributor.author | Jamali, S. | en_US |
| dc.contributor.author | Ashtiani, M.M. | en_US |
| dc.contributor.author | Milic, D. | en_US |
| dc.date.accessioned | 1399-07-08T21:49:23Z | fa_IR |
| dc.date.accessioned | 2020-09-29T21:49:23Z | |
| dc.date.available | 1399-07-08T21:49:23Z | fa_IR |
| dc.date.available | 2020-09-29T21:49:23Z | |
| dc.date.issued | 2016-06-01 | en_US |
| dc.date.issued | 1395-03-12 | fa_IR |
| dc.date.submitted | 2016-06-25 | en_US |
| dc.date.submitted | 1395-04-05 | fa_IR |
| dc.identifier.citation | Jamali, S., Ashtiani, M.M., Milic, D.. (2016). Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3( -O)BF4. Scientia Iranica, 23(3), 1089-1094. doi: 10.24200/sci.2016.3878 | en_US |
| dc.identifier.issn | 1026-3098 | |
| dc.identifier.issn | 2345-3605 | |
| dc.identifier.uri | https://dx.doi.org/10.24200/sci.2016.3878 | |
| dc.identifier.uri | http://scientiairanica.sharif.edu/article_3878.html | |
| dc.identifier.uri | https://iranjournals.nlai.ir/handle/123456789/118806 | |
| dc.description.abstract | The heterobinuclear platinum(0)-gold(I) complex [(t-Bu3P)2PtAu(PPh3)] BF4, 5, was synthesized by the reaction of trinuclear cluster complex f[(PPh3)Au]3( - O)gBF4, 4, with one equiv of [(t-Bu3P)2Pt] at room temperature. The heterobinuclear complex 5 was characterized using multinuclear NMR spectroscopy and elemental microanalysis and was further identi ed by single crystal X-ray structure determination. Crystal structure of 5 shows a T-shaped geometry with an unsupported short distance Pt-Au dative bond. | en_US |
| dc.format.extent | 2693 | |
| dc.format.mimetype | application/pdf | |
| dc.language | English | |
| dc.language.iso | en_US | |
| dc.publisher | Sharif University of Technology | en_US |
| dc.relation.ispartof | Scientia Iranica | en_US |
| dc.relation.isversionof | https://dx.doi.org/10.24200/sci.2016.3878 | |
| dc.subject | Synthesis | en_US |
| dc.subject | Metal | en_US |
| dc.subject | Complex | en_US |
| dc.subject | Platinum | en_US |
| dc.subject | Gold | en_US |
| dc.subject | Cluster | en_US |
| dc.subject | Binuclear | en_US |
| dc.title | Synthesis of a new T-shaped heterobinuclear Pt0-AuI complex [(t-Bu3P)2PtAu(PPh3)]BF4 from trinuclear gold cluster complex [(PPh3)Au]3( -O)BF4 | en_US |
| dc.type | Text | en_US |
| dc.contributor.department | Department of Chemistry, Sharif University of Technology, Tehran, P.O. Box 11155-3516, Iran. | en_US |
| dc.contributor.department | Department of Chemistry, Sharif University of Technology, Tehran, P.O. Box 11155-3516, Iran. | en_US |
| dc.contributor.department | Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia. | en_US |
| dc.citation.volume | 23 | |
| dc.citation.issue | 3 | |
| dc.citation.spage | 1089 | |
| dc.citation.epage | 1094 | |